She really is an inexperienced hunter, she didn't tie you up and often doesn't watch what you do.
You can climb out of the pot without any problems. It wouldn't be a challenge to run away. But then the cute hunter would end up empty-handed.
Before you can sneak past her, you have another opportunity to look at the little green-haired girl. Someday a hunter will catch you. But without your help this poor girl will never learn how to hunt successfully.